Her love for books has developed since Aizen regularly gave her the books he had read. In his absence, she frequently visits the library. She attends the ikebana lessons held by Captain Retsu Unohana. She frequently visits Tōshirō's grandmother in Rukongai. Her favorite food is peach, and she does not like plums. She sometimes bakes cookies, and once made a batch in the shape of Aizen's glasses. Momo is generally an upbeat, easy-going, and friendly girl. She has a strong friendship with Tōshirō Hitsugaya, whom she grew up with, repeatedly calling him "Shirō-chan", despite his higher rank and complaints about this. Though normally kind, her rare bouts of anger can appear rather menacing, such as her outrage at Captain Gin Ichimaru when she blamed him for killing Aizen. While serving as his lieutenant, Momo greatly respects and admires Aizen. She idolizes him to the point where a letter from Aizen leads her to attack Hitsugaya, her childhood friend, and even after being stabbed by Aizen, she, proclaiming Aizen was being manipulated, asks Hitsugaya to save him. When Aizen leads an attack on the Fake Karakura Town, Momo helps to defend the town from Aizen and his forces, but she still notably refers to him as "Captain Aizen". While the captains are in a meeting, the lieutenants, gathering, discuss the situation with the Wandenreich and recent disappearances of Hollows and Rukongai residents. Momo listens as Izuru deduces Shinigami were likely involved in the disappearance of the Rukongai denizens. When the Wandenreich make their attack on Soul Society, Momo and her captain quickly make their way to the battlefield. En route to the battlefield, the two sense Yamamoto's Reiatsu moving onto the battlefield. When Momo states she has never seen the Captain-Commander so angry, Shinji, scolding her, calls her an idiot. He states he has not ever seen the Captain-Commander in such a rage either. Momo is surprised to hear from her captain this will be the first time they will see Yamamoto fight at the front lines. She is told they need to hurry, or else Yamamoto will take all the fun for himself.
A few days after the Wandenreich retreat, Momo nervously listens to Shinji arguing with Hiyori Sarugaki over a phone. Later Momo bears witness to the swift and complete invasion of Soul Society by the Wandenreich. When her captain is wounded by Bambietta Basterbine, an enraged Momo tries to attack the Sternritter. She is however stopped by Sajin Komamura, who states that the explosions created by the Quincy are not something that Momo can counter with Tobiume. Komamura then protects her from the explosions. After Bambietta is defeated, Momo heals Shinji and the two go to the location of Marechiyo Ōmaeda and saves him from the advancing Soldat using Tobiume. She then proceeds to heal the wounded at her captain's order. Later, Momo arrives at the building that the captains and lieutenants are being summoned to alongside Suì-Fēng, where she greets Renji and Rukia. Inside the building, she is shocked by Urahara's intention to break into the Soul King Palace. Later, when the remaining Visored enter the building, Momo stands next to her captain and nervously watches him and Hiyori quarrel. As the Shinigami enter the Royal Realm, Momo accompanies them as they run through the city, but Lille Barro begins picking them off. When Shunsui confronts Lille, Momo gets ready to help him, but to her shock Shinji runs away instead. However, Shinji reminds her that they are in a race against time and says that both Ukitake and Yamamoto would have told them to let the Captain-Commander be. The Shinigami then reach the upper levels of the city, but are confronted by Gerard Valkyrie, who says they will have to take him on all at once to defeat him. Renji and Byakuya easily defeat Gerard, and after Byakuya finishes the Quincy off, Momo asks if he really needed to use excessive force, as Gerard looked as though he was about to die on his own. Shinji tells her that Gerard looked like he had a trump card up his sleeve, and Byakuya slams Gerard into the ground with Senbonzakura for good measure, causing Momo to wince. However, a giant foot rises and slams onto the ground and a giant Gerard then rises up. Gerard shouts at the Shinigami, pushing them back with the force of his voice, and explains how his Schrift The Miracle works as he throws an obelisk at the Shinigami. The force of the obelisk blows Momo back, but she is grabbed by Shinji. However, Gerard follows up by slamming Momo and Shinji into the ground. Kidō Expert: Momo excels at Kidō. Captain Hitsugaya and Izuru have stated Momo is a Kidō master. She can use multiple spells in conjunction with each other and her Zanpakutō, creating a unique way in which to attack and incapacitate her opponents. In this way, she can make common spells all her own. She can use a single Kidō technique on two separate targets at once. Momo has some skill with healing Kidō. Expert Swordsman: Momo is proficient enough to cross swords with other lieutenant-level Shinigami. While she is capable enough in swordsmanship to attain her high-level seated position, when facing Harribel's Fracción, she states she knows she is not strong enough to combat them using her swordsmanship skills, instead sneaking up on them and using Kidō. Shunpo Practitioner: Momo is skilled enough in the use of Shunpo to keep up with lieutenant-level Shinigami. High Spiritual Power: Being a lieutenant of the Gotei 13, Momo boasts a high level of spiritual energy. Her Reiatsu is red. Skilled Tactician: Knowing her own limitations in direct battle, Momo has shown herself able to compensate for it through crafty combination attacks (such as when she caught Sung-Sun, Mila Rose, and Apacci in a Kidō net). Because of her expertise in Kidō, Momo is able to attack in a number of versatile ways.
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